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Defect of the Month

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Monster Teeth
Monster Teeth
April, 2023

In this magnified view of a cobalt-colored bottle, a series of individual knurls are partially illuminated as large blue crescents. The smaller, vertical cracks running through two of the knurls are flaws referred to as “bearing surface checks.” Bearing surface checks are most often created when rough handling causes damage to the bottom soon after bottle formation. This damage is then extended into checks due to thermal stresses caused by temperature differences between the glass and the transfer or conveyer surfaces. Bearing surface checks may lower the performance of a container subjected to loads such as impact, internal pressure, and thermal shock.

Four-Leaf Clover
Four-Leaf Clover
March, 2023

What do leprechauns and annealing stresses have in common? They’re both invisible! Or at least, usually invisible. This photograph shows the bottom portion of a green glass bottle under polarized light (crossed polars), which is necessary to view annealing stress. The bright “four-leaf clover” pattern is due to a combination of retardation caused by annealing stress and the optical configuration of the polarimeter. Following procedures described in ASTM C148, the amount of retardation can be measured and assigned an integer value called a “temper grade,” which is a good metric for annealing quality.

Grapes of Wrath
Grapes of Wrath
February, 2023

Like the John Steinbeck novel of the same title, this colorized SEM image has virtually nothing to do with grapes. When an organic (i.e. carbonaceous) material such as rubber, oil, or grease enters a bottle in the hot-end of a glass plant, temperatures in excess of 700°C cause it to instantly combust. Under some conditions, soot particles can be produced due to the condensation of vaporized organic matter. The spherical soot particles in this image (blue/purple) were created by combustion of an organic contaminant inside of a glass bottle. The radiating needle-like clusters (brown) are composed of sodium carbonate (Na2CO3), likely due to sodium in the burning material. The background (green) is an amorphous carbonized residue.

Drop of Gold
Drop of Gold
January, 2023

Glass can be produced in a kaleidoscope of colors through the inclusion of small amounts of metal oxides in the glass composition. In the art glass industry, where color is paramount, exotic metals or metal oxides can be used that would be cost-prohibitive for food or beverage containers. Since the late Roman empire, gold has been known to create vivid red hues when added to glass. Although the host glass in this microscopic image is not red-colored, this particular stone is composed of excess gold that lingered in an art glass furnace from a prior batch.